Basic dyes are the sensitive chromogenic agents for precious metals determination by photometry.This paper analyzed about 200 kinds of this super-high sensitive chromogenic systems(e106 L/mol·cm).Through contrasting research it has been found out that the keys to get super-high sensitive chromogenic systems are that create suitable conditions for forming a complicated ionic association precipitate through precious metal's comlex anion with dye cation,and try transferring the complicated precipitate and above-quota companying dye molecules to the solution equably so that they are suitable for next-step determination.