Bulk and interface engineering of Prussian blue analogue cathodes for high-performance sodium-ion batteries

. Additionally, interface-related issues, such as side reactions and the dissolution of transition metal ions, severely limit the reversible capacity and cycle stability of PBA-based cathode materials. Therefore, addressing these challenges from the bulk and interface of PBAs is critical for the development of high-performance cathode materials for SIBs. This review aims to provide insights into potential strategies for overcoming these limitations and enhancing the electrochemical performance of PBAs. Firstly, the structure, morphology, and reaction mechanisms of PBAs are summarized systematically. The key challenges hindering the commercialization of PBAs are then categorized in this review. Several effective strategies for addressing these challenges are provided, including bulk phase engineering (thermal treatment, element doping, and etching), interface engineering (coating, ion exchange, and electrolyte additives), and the co-regulation of bulk and interface. Finally, the future commercialization prospects of PBAs are discussed, highlighting the necessary steps for transitioning from laboratory-scale research to industrial-scale production.