区域选择性
立体选择性
化学
催化作用
硼
有机化学
摘要
A highly efficient β-arabinofuranosylation utilizing boron-mediated aglycon delivery (BMAD) is presented by Kazunobu Toshima, Daisuke Takahashi, and co-workers in their Research Article (e202307015). The glycosylations proceeded smoothly for a variety of diols, triols, and unprotected sugar acceptors under mild conditions with predictable regioselectivity and complete β-stereoselectivity. Furthermore, the cover image shows that the regioselectivity in the BMAD reaction could be reversed by examining the reaction conditions and catalyst.
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