锌
腐蚀
金属
化学
硝基
离子
阳极
配位复合体
水溶液中的金属离子
无机化学
冶金
材料科学
物理化学
电极
有机化学
烷基
作者
Jizhen Wang,Long Jiao,Qiaoyun Liu,Xiaoyang Wei,Yechen Lei,Tian Zhang,Long Yang,Dengkun Shu,Shuo Yang,Kaihua Li,Chen‐Yang Li,Yi Chen,Hao Bai,Yue Ma,Huan Li,Wenjun Zhang,Bowen Cheng
标识
DOI:10.1016/j.jechem.2024.02.034
摘要
Suppression of uncontrollable dendrite growth and water-induced side reactions of Zn metal anodes is crucial for achieving long-lasting cycling stability and facilitating the practical implementations of aqueous Zn-metal batteries. To address these challenges, we report in this study a functional nitro-cellulose interfacial layer (NCIL) on the surface of Zn anodes enlightened by a nitro-coordination chemistry strategy. The NCIL exhibits strong zincophilicity and superior coordination capability with Zn2+ due to the highly electronegative and highly nucleophilic nature of the nitro functional group. This characteristic facilitates a rapid Zn-ion desolvation process and homogeneous Zn plating, effectively preventing H2 evolution and dendrite formation. Additionally, the negatively charged surface of NCIL acts as a shield, repelling SO42− anions and inhibiting corrosive reactions on the Zn surface. Remarkably, reversible and stable Zn plating/stripping is achieved for over 5100 h at a current density of 1 mA cm− 2, which is nearly 30 times longer than that of bare Zn anodes. Furthermore, the Zn//V2O5 full cells with the functional interface layer deliver a high-capacity retention of 80.3% for over 10,000 cycles at 5A g− 1. This research offers valuable insights for the rational development of advanced protective interface layers in order to achieve ultra-long-life Zn metal batteries.
科研通智能强力驱动
Strongly Powered by AbleSci AI