光热治疗
催化作用
材料科学
尖晶石
光热效应
热液循环
纳米技术
化学工程
化学
有机化学
冶金
工程类
作者
Ang Zhou,Xiaolin Guo,Siyi Zhong,Zi'ang Chen,Qiaoling Kang,Miaogen Chen,Dingfeng Jin,Meiqiang Fan,Renxian Zhou,Tingli Ma
标识
DOI:10.1016/j.cej.2023.144835
摘要
A novel strategy with the "three birds, one stone" effect has been proposed to enhance the catalytic performance of cobalt manganese spinel catalysts for photothermal CO-PROX in H2 streams. The approach involves fabricating hierarchically arrayed defective MnCo2O4@ Nickel foam (NF) through a simple hydrothermal post-treatment and partial recrystallization process. Three synergetic effects were induced by the hydrothermal posttreatment of MnCo2O4: (i) the creation of a hierarchically arrayed morphology that strengthens light absorption and photo-to-thermal conversion, supported by finite-element method (FEM) simulations; (ii) the increased vacancy structures to alleviate significant electron-hole recombination; and (iii) abundant oxygen vacancy to facilitate oxygen adsorption and activation. These effects result in the unique hierarchically arrayed morphology and superior structural properties of MnCo2O4 spinel, which significantly enhances the photothermal synergism and catalytic activity of MnCo2O4@NF in photothermal CO-PROX driven by simulated solar light. This work provides a simple and facile strategy for developing hierarchical and defective MnCo2O4 spinel photothermal materials.
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