A Stretchable, Breathable, And Self‐Adhesive Electronic Skin with Multimodal Sensing Capabilities for Human‐Centered Healthcare

Abstract Electronic skins (E‐skins) capable of biomechanical/bioelectrical signal acquisition are intensively pursued for human‐centered healthcare of daily life. For practical use, it is highly desired, yet challenging, to mass‐produce E‐skins that are soft and breathable for wearing comfort, skin‐adhesive for robust signal acquisition, multi‐signal sensing for enhanced healthcare data. Herein, a scalable fabrication strategy for a bioinspired E‐skin (SPRABE‐skin) with a multi‐layered architecture is reported that integrates skin‐like softness, self‐protection, self‐adhesion, breathability, and bimodal sensing in a single patch. The fibrous thermoplastic polyurethane (TPU) scaffold endows the SPRABE‐skin with tissue‐like softness (Young's modulus of 3.36 MPa) and stretchability, good permeability to water vapor, and self‐protection against adverse loading events. A strain sensing layer composed of MXene‐carbon nanotubes@TPU (MXene‐CNT@TPU) composition exhibits ultra‐high sensitivity in a wide sensing range (gauge factor at strain of 485% reaches 63 494). An electrode layer made of MXene‐waterborne polyurethane (MXene‐WPU) provides a highly adhesive electrode‐skin interface, which enables the acquisition of biopotentials, such as electrocardiograph (ECG), electromyograph (EMG), electroencephalo‐graph (EEG), with improved fidelity even under various dynamic interferences. Finally, a SPRABE‐skin based human‐centered healthcare system is demonstrated that realizes the wireless, long‐duration, and dynamic monitoring of ECG and running activities.