阳极
枝晶(数学)
阴极
化学工程
锂(药物)
材料科学
沸石
电解质
沉积(地质)
多孔性
无机化学
化学
电极
复合材料
催化作用
物理化学
有机化学
医学
古生物学
几何学
数学
沉积物
工程类
生物
内分泌学
作者
Ben Su,Xingyu Wang,Linjiang Chai,Sida Huo,Jingyi Qiu,Qiang Huang,Shuang Li,Yue Wang,Wendong Xue
标识
DOI:10.1002/advs.202308939
摘要
Abstract Lithium metal, with ultrahigh theoretical specific capacity, is considered as an ideal anode material for the lithium‐ion batteries. However, its practical application is severely plagued by the uncontrolled formation of dendritic Li. Here, a cation‐loaded porous Mg 2+ ‐Zeolite layer is proposed to enable the dendrite‐free deposition on the surface of Li metal anode. The skeleton channels of zeolite provide the low coordinated Li + ‐solvation groups, leading to the faster desolvation process at the interface. Meanwhile, anions‐involved solvation sheath induces a stable, inorganic‐rich SEI, contributing to the uniform Li + flux through the interface. Furthermore, the co‐deposition of sustained release Mg 2+ realizes a new faster migration pathway, which proactively facilitates the uniform diffusion of Li on the lithium substrate. The synergistic modulation of these kinetic processes facilitates the homogeneous Li plating/stripping behavior. Based on this synergistic mechanism, the high‐efficiency deposition with cyclic longevity exceeding 2100 h is observed in the symmetric Li/Li cell with Mg 2+ ‐Zeolite modified anode at 1 mA cm −2 . The pouch cell matched with LiFePO 4 cathode fulfills a capacity retention of 88.4% after 100 cycles at a severe current density of 1 C charge/discharge. This synergistic protective mechanism can give new guidance for realizing the safe and high‐performance Li metal batteries.
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