吸附
阳离子聚合
壳聚糖
化学
朗缪尔吸附模型
化学工程
亚甲蓝
核化学
醋酸
复合数
材料科学
有机化学
复合材料
催化作用
光催化
工程类
作者
Xiaolin Zhao,Xue Jun Wang,Tao Lou
标识
DOI:10.1016/j.jhazmat.2020.124054
摘要
Natural polysaccharide is attractive for preparing the environmentally friendly and highly efficient adsorbent. However, to obtain an efficient amphoteric absorbent for dealing with complex wastewater is still challenging. Herein, fibrous chitosan/sodium alginate composite foams were prepared by lyophilization with ternary acetic acid/water/tetrahydrofuran solvents, which had suitable morphology of interconnected pores and microscale fibers for dye adsorption. The amphoteric composite foams showed high adsorption capacities for both anionic Acid Black-172 (817.0 mg/g) and cationic Methylene Blue (1488.1 mg/g), which were far superior to those of the control samples prepared with traditional solvents of acetic acid/water. The adsorption kinetics and isotherm data showed that the adsorption followed the pseudo-second-order and Langmuir model. Further thermodynamics analysis revealed the adsorption was a spontaneous process. Meanwhile, the foams achieved effective adsorption capacity of AB-172 and MB dyes under a wide range of environmental pH, and maintained high adsorption efficiency even after four cycles. The adsorption mechanism is chemisorption, where the adsorption capacities for the anionic and cationic dyes were dependent on the mass ratio of chitosan to sodium alginate. As a novel amphoteric adsorbent, the fibrous chitosan/sodium alginate composite foam shows the potential to remove both cationic and anionic dyes from wastewaters.
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