过电位
化学
电催化剂
密度泛函理论
离解(化学)
钛
吸附
表面改性
化学工程
无机化学
纳米技术
电化学
物理化学
电极
计算化学
有机化学
工程类
材料科学
作者
Ling Zhang,Ibrahim Saana Amiinu,Xiang Ren,Zhiang Liu,Guoping Du,Abdullah M. Asiri,Baozhan Zheng,Xuping Sun
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2017-11-07
卷期号:56 (22): 13651-13654
被引量:85
标识
DOI:10.1021/acs.inorgchem.7b02466
摘要
Interface engineering has been demonstrated to be effective in promoting hydrogen evolution reaction (HER) in an alkaline solution. Herein, we report that the HER activity of a NiS2 nanoarray on a titanium mesh (NiS2/TM) in alkaline media is greatly boosted by the electrodeposition of Ni(OH)2 onto NiS2 [Ni(OH)2-NiS2/TM]. Ni(OH)2-NiS2/TM only needs an overpotential of 90 mV to deliver 10 mA cm-2 in 1.0 M KOH. Density functional theory calculations confirm that Ni(OH)2-NiS2 has a lower water dissociation free energy and a more optimal hydrogen adsorption free energy than NiS2.
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