化学
铀酰
热重分析
三嗪
金属有机骨架
水溶液
分子
吸附
拓扑(电路)
溶剂热合成
结晶学
无机化学
物理化学
高分子化学
有机化学
离子
组合数学
数学
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2019-05-09
卷期号:58 (10): 6866-6876
被引量:53
标识
DOI:10.1021/acs.inorgchem.9b00317
摘要
A novel uranyl–organic framework [(CH3)2NH2][UO2(TATAB)]·2DMF·4H2O (U-TATAB) was assembled through the solvothermal synthesis of UO2(CH3COO)2·2H2O and triazine tricarboxylate linker H3TATAB (H3TATAB = 4,4′,4″-s-triazine-1,3,5-triyltri-p-aminobenzoate). It was characterized by single-crystal X-ray diffraction, elemental analysis, IR, powder X-ray diffraction, and thermogravimetric microanalysis. It is worth mentioning that U-TATAB exhibits an original arrangement of structures with interesting topology. Structural analysis confirmed that U-TATAB displays an interesting two-dimensional graphene-like layered topology. In order to broaden its functional characteristics, we first investigated the functional adsorbent U-TATAB for iodine capture in cyclohexane solution and for the removal of dye in aqueous solution. Large porosity, unique structure character, and the π-electron walls made of TATAB make the material a promising functional absorbent exhibiting excellent adsorption performance for iodine and dye molecules. Most notably, this is the first case of a uranyl–organic framework built by secondary building unit (SBU) [UO2(RCOO)3]– and extended trigonal triazine tricarboxylate ligand H3TATAB with amino functional groups.
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