光催化
钨酸盐
煅烧
催化作用
石墨氮化碳
复合数
三聚氰胺
化学工程
材料科学
化学
无机化学
核化学
光化学
有机化学
复合材料
工程类
作者
Huili Zhang,Zhiyuan Feng,Yekun Zhu,Ying Wu,Tinghua Wu
标识
DOI:10.1016/j.jphotochem.2018.10.044
摘要
WO3/g-C3N4 (graphitic carbon nitride) composite was prepared via a directly calcination method with ammonium tungstate hydrate and melamine as raw materials, and applied in the photocatalytic oxidation of 5-hydroxymethylfurfural (5-HMF) to 2,5-diformylfuran (DFF) for the first time. Its physicochemical properties were characterized by HR(TEM), XRD, FT-IR, XP, UV-vis, PL, PC and EIS methods. The results revealed that the doping of WO3 into g-C3N4 can reduce the possibility of charge recombination and thus enhancing the photocatalytic activity. The impact factor, such as incident wavelength, reaction time, and solvent were also studied on the photocatalytic behavior. 4.7%WO3/g-C3N4 composite catalyst exhibits the highest 5-HMF conversion of 27.4% with DFF selectivity of 87.2% under the irradiation of visible-light (>400 nm). As the active species, O2− and h+ plays an important role to convert 5-HMF to DFF. Finally, the Z-scheme mechanism and reaction route were proposed by combining the photocatalytic performance with the active oxygen species research of the WO3/g-C3N4 catalyst.
科研通智能强力驱动
Strongly Powered by AbleSci AI