三乙胺
硼烷
化学
试剂
小学(天文学)
羧酸
有机化学
溶剂
催化作用
组合化学
物理
天文
作者
Otomar Kříž,Zbyněk Plzák,Jaromir Plesek
出处
期刊:ChemPlusChem
[Wiley]
日期:1990-01-01
卷期号:55 (12): 2956-2962
被引量:11
摘要
Triethylamine borane, (C2H5)3N.BH3, is a stable, safe and readily available reagent which at 80 °C reduces carboxylic acids to primary alcohols in high yields; functional derivatives of carboxylic acids such as esters, nitriles or amides are virtually nonreactive with this reagent under the same conditions. Aldehydes, ketones and acid chlorides, however, react readily. No solvent is required for the process.
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