选择性
材料科学
巴勒
膜
溶解度
化学工程
PEG比率
聚合物
石墨烯
聚乙二醇
氧化物
乙二醇
聚乙烯亚胺
胺气处理
有机化学
高分子化学
纳米技术
化学
复合材料
催化作用
生物化学
财务
工程类
经济
冶金
转染
基因
作者
Xueqin Li,Youdong Cheng,Haiyang Zhang,Shaofei Wang,Zhongyi Jiang,Ruili Guo,Hong Wu
标识
DOI:10.1021/acsami.5b00106
摘要
A novel multi-permselective mixed matrix membrane (MP-MMM) is developed by incorporating versatile fillers functionalized with ethylene oxide (EO) groups and an amine carrier into a polymer matrix. The as-prepared MP-MMMs can separate CO2 efficiently because of the simultaneous enhancement of diffusivity selectivity, solubility selectivity, and reactivity selectivity. To be specific, MP-MMMs were fabricated by incorporating polyethylene glycol- and polyethylenimine-functionalized graphene oxide nanosheets (PEG–PEI–GO) into a commercial low-cost Pebax matrix. The PEG–PEI–GO plays multiple roles in enhancing membrane performance. First, the high-aspect ratio GO nanosheets in a polymer matrix increase the length of the tortuous path of gas diffusion and generate a rigidified interface between the polymer matrix and fillers, enhancing the diffusivity selectivity. Second, PEG consisting of EO groups has excellent affinity for CO2 to enhance the solubility selectivity. Third, PEI with abundant primary, secondary, and tertiary amine groups reacts reversibly with CO2 to enhance reactivity selectivity. Thus, the as-prepared MP-MMMs exhibit excellent CO2 permeability and CO2/gas selectivity. The MP-MMM doped with 10 wt % PEG–PEI–GO displays optimal gas separation performance with a CO2 permeability of 1330 Barrer, a CO2/CH4 selectivity of 45, and a CO2/N2 selectivity of 120, surpassing the upper bound lines of the Robeson study of 2008 (1 Barrer = 10–10 cm3 (STP) cm–2 s–1 cm–1 Hg).
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