立体选择性
化学
烯丙基重排
磺酰
区域选择性
组合化学
有机化学
立体化学
催化作用
烷基
作者
Zhiyuan Huang,Qingquan Lu,Yichang Liu,Dong Liu,Jian Zhang,Aiwen Lei
出处
期刊:Organic Letters
[American Chemical Society]
日期:2016-08-02
卷期号:18 (16): 3940-3943
被引量:48
标识
DOI:10.1021/acs.orglett.6b01575
摘要
A highly regio- and stereoselective oxysulfonylation of allenes was developed that provided direct access to 2-sulfonyl allylic alcohols in good yields. By means of dioxygen activation, selective difunctionlization of allenes could be successfully achieved under mild metal-free conditions. Preliminary mechanistic investigation disclosed that this transformation probably goes through a radical process.
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