化学
三斜晶系
重氮甲烷
芘
无定形固体
位阻效应
结晶学
群(周期表)
相(物质)
光化学
Crystal(编程语言)
晶体结构
有机化学
计算机科学
程序设计语言
作者
Feng Xu,Takanori Nishida,K. Shinohara,Lifen Peng,Makoto Takezaki,Takahiro Kamada,Hidetoshi Akashi,Hiromu Nakamura,Kouki Sugiyama,Kazuchika Ohta,Akihiro Orita,Junzo Otera
出处
期刊:Organometallics
[American Chemical Society]
日期:2017-01-12
卷期号:36 (3): 556-563
被引量:23
标识
DOI:10.1021/acs.organomet.6b00781
摘要
Substitution of 1,3,6,8-tetraethynylpyrene with sterically bulky trimethylsilyl groups enabled four modes of molecular packing, two polymorphs (triclinic system (Y-form) and “loose” crystal Colho (OK-form)), a ”rigid” liquid crystalline phase Colho (OC-form), and an amorphous phase (OA-form), which emitted fluorescence at different wavelengths under UV light. The four phases could be interconverted by physical stimuli such as heating, grinding by mortar and pestle, and exposing to the vapor of organic solvents.
科研通智能强力驱动
Strongly Powered by AbleSci AI