聚氨酯
异氰酸酯
材料科学
胺气处理
聚合物
低聚物
高分子化学
化学工程
化学
有机化学
复合材料
工程类
标识
DOI:10.1002/marc.202200663
摘要
Herein, the rational design of an enaminone compound is reported which can be easily and conveniently designed and obtained via the reaction of amine and diketone. The dynamic enaminoneamide structure is formed via the reaction between isocyanate and enaminone in fabricating a novel dynamic crosslinked polyurethane. The new kind of polyurethane can be efficiently recycled via the shifting between crosslinked structure and oligomer for the reversible dissociation of the enaminoneamide structure. Besides remolding itself via the thermal treatment, oligomers liberated from recycled-polyurethane can directly take part in constructing a new polyurethane without further purification. Therefore, the recyclability of this polyurethane shows high-value characteristics. The ease with which polyurethane can be produced, used, recycled, and reused without losing value offers a new green solution in designing sustainable polymer materials with a high economic value and a minimal environmental burden.
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