电解质
超级电容器
离子液体
材料科学
电极
电化学
多孔性
电容
化学工程
碳纤维
离子
电化学窗口
复合材料
离子电导率
化学
有机化学
复合数
工程类
物理化学
催化作用
作者
Yuhua Zhao,Yujuan Chen,Quanzhou Du,Kelei Zhuo,Lifang Yang,Dong Sun,Guangyue Bai
出处
期刊:Materials
[MDPI AG]
日期:2022-10-21
卷期号:15 (20): 7400-7400
被引量:2
摘要
Ionic liquids (ILs), with their wide electrochemical stable potential window, are promising electrolytes for supercapacitors (SCs). The suitable matching of the ion size and shape of the ILs to the pore size and structure of porous carbon (PC) electrode materials can realize the enhanced capacitive performance of the SCs. Here we report an interesting result: The capacitance of PC-based SCs shows a quasi-sinusoidal relationship with the composition (mass fraction) of the binary IL mixture as the electrolyte. This relationship is also interpreted based on the matching between the pore sizes of the PC materials and the size/shape of various ions of the IL mixture electrolyte. This can provide a new strategy to improve the performance of SCs by formulating a suitable mixture of different ILs to match the carbon-based electrode materials with a special pore size distribution.
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