Xylan derived fluorescence carbon dots composite with cotton cellulose paper as ‘turn-off’ fluorescence platform for sensitive and selective detection Cu2+ in real samples

The pollution of heavy metals such as Cu2+ is still serious and the discharge of sewage of Cu2+ will cause damage to soil environment and human health. Herein, a biomass-based solid-state fluorescence detection platform (CPU-CDs) was developed as fluorescent sensor for detection Cu2+ via fluorescence and colorimetric dual-model methods in real time. CPU-CDs was composed of xylan-derived CDs (U-CDs) and cotton cellulose paper, which exhibiting good reusability, non-toxicity, excellent fluorescence characteristics and high biocompatibility. Further, CPU-CDs displayed high effectiveness and sensitivity for Cu2+ with the detection limit as low as 0.14 μM, which was well below U.S. EPA safety levels (20 μM). Practical application indicated that CPU-CDs could achieve precision response of Cu2+ change in real environment water samples with good recovery range of 90 %–119 %. This strategy demonstrated a promising biomass solid-state fluorescence sensor for Cu2+ detection for water treatment research, which is of great significance in dealing with water pollution caused by heavy metal ions.