Biomass-based porous carbon for high-performance supercapacitor electrode materials prepared from Canada goldenrod

超级电容器 电容 碳化 材料科学 碳纤维 生物量(生态学) 活性炭 电解质 化学工程 电化学 水溶液 储能 原材料 电极 功率密度 复合材料 化学 有机化学 生态学 功率(物理) 扫描电子显微镜 物理 物理化学 吸附 量子力学 复合数 工程类 生物
作者
Jianfei Tu,Zhijun Qiao,Yuzuo Wang,Gaofeng Li,Gaofeng Li,Xi Zhang,Guoping Li,Guoping Li,Dianbo Ruan
出处
期刊:Journal of energy storage [Elsevier BV]
卷期号:73: 109268-109268 被引量:48
标识
DOI:10.1016/j.est.2023.109268
摘要

Preparing activated carbon from biomass materials that can be used as electrode materials for supercapacitors is crucial for realizing new green energy storage and conversion technologies to fulfill environmental requirements. Herein, activated carbon was prepared via high-temperature carbonization and KOH activation using Canada goldenrod as a raw material, which is a serious threat to the ecological environment. Using this activated carbon as the active material and 6 M KOH and 1 M TEABF4/AN as the electrolytes, aqueous and organic coin-cell symmetrical supercapacitors were prepared, respectively. The specific capacitance of activated carbon was calculated to reach 320 and 123 F/g at a current density of 0.1 A/g during its testing in a two-electrode system, corresponding to energy densities of 40 and 112.1 Wh/kg, respectively. The power density of the aqueous supercapacitor was 9 KW/Kg at 10 A/g, while that of the organic supercapacitor was 12.2 KW/Kg at 5 A/g; after 10,000 cycles of the charge–discharge test, the capacity retention rate reached 93.6 % and 86.4 %, indicating the excellent electrochemical performance of the prepared supercapacitor. In addition, the specific capacitance reached 366 and 252 F/g at capacitance densities of 0.1 and 0.5 A/g, respectively, during its testing in a three-electrode system. The results of this study indicate that Canada goldenrod is a good biomass-based precursor material for preparing porous carbon for supercapacitors.
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