异质结
光催化
材料科学
复合数
表面等离子共振
纳米颗粒
热液循环
化学工程
废水
纳米复合材料
肖特基势垒
贵金属
纳米技术
化学
光电子学
金属
催化作用
复合材料
环境工程
环境科学
冶金
工程类
二极管
生物化学
作者
Yangjie Fu,Youran Xu,Yanjie Mao,Meng Tan,Qiaojun He,Huixiu Mao,Hao Du,Derek Hao,Qi Wang
标识
DOI:10.1016/j.seppur.2023.123922
摘要
Environmental issues caused by various pollutants has aroused wide concern. Designing S-scheme heterojunction photocatalysts has been a promising approach. Strengthening its efficient charge transport routes with the assist of noble metal nanoparticles is potential to achieve high-efficiency wastewater treatment. An improved S-scheme heterojunction Ag/Ag3PO4/Ag3PMo12O40 (Ag/Ag3PO4/AgPMo) was fabricated via the hydrothermal method and in-situ UV reduction process. The loading of Ag0 led to multiple effects: a broad spectral response and a sufficient charge transfer via surface plasmon resonance (SPR) and the Schottky effect. The as-prepared Ag/Ag3PO4/AgPMo composite can completely reduce Cr(VI) within 90 min under visible light, and the rate constant attained 0.029 min−1, which was 29.0 times that by pure AgPMo. Moreover, the composite also displayed excellent tetracycline hydrochloride (TC) removal efficiency, and the value was 97% within 180 min. Interestingly, efficient treatment can also be applied to mixed wastewater containing organic matters (i. e. phenol, dyes, EDTA-2Na) and Cr(VI). The boosted performance can be ascribed to a stepwise path of charge transfer, which is an improved S-scheme heterojunction assisted by multi-effect Ag nanoparticles. Overall, this study opens a new strategy for the preparation of polyoxometalate-based composite for the photocatalytic disposal of hazardous pollutants.
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