发光
玻尔兹曼常数
材料科学
分析化学(期刊)
离子
光子上转换
镧系元素
兴奋剂
纳米晶
温度计
物理
纳米技术
化学
热力学
光电子学
色谱法
量子力学
作者
Linxuan Wang,Liang Li,Maohui Yuan,Zining Yang,Kai Han,Hongyan Wang,Xiaojun Xu
标识
DOI:10.1186/s11671-022-03718-z
摘要
Abstract Spectrally determination of temperature based on the lanthanide-doped nanocrystals (NCs) is a vital strategy to noninvasively measure the temperature in practical applications. Here, we synthesized a series of SrF 2 :Yb 3+ /Ho 3+ NCs and simultaneously observed the efficient visible upconversion luminescence (UCL) and near-infrared (NIR) downconversion luminescence (DCL) under 980, 940 and 915 nm excitations. Subsequently, these NCs were further utilized for thermometers based on the Boltzmann (thermally coupled levels, TCLs) and non-Boltzmann (non-thermally coupled levels, NTCLs) of Ho 3+ ions in the first (~ 650 nm), second (~ 1012 nm) and third (~ 2020 nm) biological windows (BW-I, BW-II and BW-III) under tri-wavelength excitations. The thermometric parameters including the relative sensitivity ( $$S_{{\text{r}}}$$ S r ) and temperature uncertainty ( $$\delta T$$ δ T ) are quantitatively determined on the I 648 / I 541 (BW-I), I 1186 / I 1012 (BW-II), and I 1950 / I 2020 (BW-III) transitions of Ho 3+ ions in the temperature range of 303–573 K. Comparative experimental results demonstrated that the thermometer has superior performances.
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