Artificial UV and natural ageing of polycarbonate/poly(butylene terephthalate) binary blend and reprocessing of aged blends

聚碳酸酯 材料科学 聚合物混合物 聚对苯二甲酸乙二醇酯 复合材料 老化 高分子化学 高分子科学 聚合物 共聚物 遗传学 生物
作者
Emel Kuram,Babür Özçelik,Omer Faruk Sarman,Hürol Koçoğlu,H. Ayas,Mehmet Doğan
出处
期刊:Journal of Elastomers and Plastics [SAGE Publishing]
卷期号:57 (4): 498-523 被引量:2
标识
DOI:10.1177/00952443251324178
摘要

In this research, the effect of reprocessing for aged polycarbonate (PC)/poly (butylene terephthalate) (PBT) blends was determined on the mechanical properties (tensile, impact, flexural), melt flow index and morphology. Virgin PC/PBT blends were injection molded as the tensile, flexural and impact samples to evaluate the mechanical, rheological, and morphological properties. After that, samples were exposed to artificial accelerated ageing in an QUV chamber (simulating outdoor weathering with alternating cycles of ultraviolet (UV) light and moisture at controlled elevated temperature) for up to 336 hours and natural ageing in Gebze (Turkey) for up to 1 year between May 2017 and May 2018. After these ageing processes, naturally and UV aged specimens were ground, and the ground specimens were mixed with virgin PC/PBT blends at different ratios (25%, 50% and 75% by weight). The mixed materials were re-molded to fabricate test specimens and then characterized. In summary, in current study, the mechanical, rheological, and morphological properties of virgin, aged in natural for 12 months, aged in UV chamber for 336 hours and mixture of virgin-aged PC/PBT were investigated.
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