热重分析
嫁接
纳米纤维
纤维素
表面改性
材料科学
化学工程
核化学
热稳定性
纳米纤维素
浸出(土壤学)
硅烷
丙酮
傅里叶变换红外光谱
接触角
水溶液
壳聚糖
溶剂
化学
高分子化学
吸附
涂层
抗菌剂
纳米颗粒
有机化学
纳米技术
聚合物
土壤水分
土壤科学
工程类
环境科学
作者
Seema Saini,Mohamed Naceur Belgacem,Marie-Christine Brochier Salon,Julien Bras
出处
期刊:Cellulose
[Springer Nature]
日期:2016-01-05
卷期号:23 (1): 795-810
被引量:63
标识
DOI:10.1007/s10570-015-0854-1
摘要
Uncontrolled growth of bacteria is always a major concern for various industries such as food, cosmetic and pharmaceutical industries. Taking this issue into account, a non-leaching antimicrobial surface was developed using cellulose nanofibers with a post grafting green method to mimic the antibacterial activity of chitosan. A series of experiments was designed for silylation of nanofibers with 3-aminopropyl trimethoxysilane, varying the initial concentration of silane and the solvent employed during the grafting. The results, validated by Fourier transform infrared spectroscopy, thermogravimetric analysis and elemental analysis, provided evidence of successful functionalization. Moreover, SEM–EDX indicated that a heterogeneous grafting occurred at the surface and cross section of the film. Strong antimicrobial activity against gram positive (Bacillus subtilis and Staphylococcus aureus) and gram negative (Escherichia coli) was recorded. In aqueous solution, the optimum results were obtained using grafting silane concentration of 50 g/L. The grafted CNF showed no change in the morphology or thermal stability, meanwhile a significant reduction in bacterial concentration of 1.3 logs for B. subtilis, 1.8 log for S. aureus and 3.8 logs for E. coli was observed. Regarding the solvent used during the grafting, acetone showed the reversibility of bonds between silanol groups and cellulose nanofibers or high self-condensation reaction which was depicted by the Si NMR and formation of zones of inhibition. Furthermore, water employed as grafting solvent depicted better grafting efficiency than acetone, 10.2 versus 6.4 % respectively, at the similar concentration with apparent lower grafting time.
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