碳化
烧焦
活性炭
比表面积
多孔性
吸附
打赌理论
化学工程
材料科学
体积热力学
介孔材料
碳纤维
化学
有机化学
复合材料
热解
复合数
催化作用
工程类
物理
量子力学
作者
Juejun Katesa,Chaiyot Tangsathitkulchai
摘要
This research focused on investigating the effect of the carbonization temperature on the porous properties (surface area, pore volume, and mean pore size) of coconut shell based activated carbon prepared by physical activation with carbon dioxide. The carbonization temperature was varied in the range from 250-750 o C and the derived chars were activated in CO2 at 850 o C for 60 and 120 min. The porous properties of the activated carbons obtained including the Brunauer-EmmettTeller (BET) surface area, pore volume, pore size distribution, and average pore diameter were determined by nitrogen adsorption isotherms at -196 o C. The experimental results showed that most pores occurred during the activation predominantly as micropores with a small proportion of mesopores. The porous properties of the activated carbon decreased with the increase in the carbonization temperature,with the char prepared at the lowest carbonization temperature of 250 o C and activated at 850 o C for 120 min giving activated carbon with the highest BET surface area and pore volume of 1056 m 2 /g and 0.533 cm 3 /g, respectively. From the obtained results, it is feasible to produce activated carbon with high porous properties from coconut shell by selecting the appropriate conditions for the carbonization and activation steps.
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