Elastic Yielding in Cold Drawn Polymer Glasses Well below the Glass Transition Temperature

This Letter reports elastic-driven internal yielding in strained ductile polymer glasses. After cold drawing of two different polymer glasses to neck at room temperature, we show that the samples display considerable retractive stress when warmed up above the storage temperature but still considerably below their glass transition temperatures. We conclude that the elastic yielding arises from the distortion of backbones leading to intra-segmental tension in the chain network.