光致发光
色度
钙钛矿(结构)
量子点
激发态
吸收(声学)
材料科学
光电子学
发光
光子学
大气温度范围
化学
原子物理学
光学
物理
结晶学
气象学
复合材料
作者
Ke Wei,Zhongjie Xu,Runze Chen,Xin Zheng,Xin Cheng,Tian Jiang
出处
期刊:Optics Letters
[The Optical Society]
日期:2016-08-09
卷期号:41 (16): 3821-3821
被引量:249
摘要
Recently, lead halide perovskite quantum dots have been reported with potential for photovoltaic and optoelectronic applications due to their excellent luminescent properties. Herein excitonic photoluminescence (PL) excited by two-photon absorption in perovskite CsPbBr3 quantum dots (QDs) has been studied at a broad temperature range, from 80 to 380 K. Two-photon absorption has been investigated and the absorption coefficient is up to 0.085 cm/GW at room temperature. Moreover, the PL spectrum excited by two-photon absorption shows a linear blue-shift (0.32 meV/K) below the temperature of 220 K. However, for higher temperatures, the PL peak approaches a roughly constant value and shows temperature-independent chromaticity up to 380 K. This behavior is distinct from the general red-shift for semiconductors and can be attributed to the result of thermal expansion, electron-phonon interaction and structural phase transition around 360 K. The strong nonlinear absorption and temperature-independent chromaticity of CsPbBr3 QDs observed in temperature range from 220 to 380 K will offer new opportunities in nonlinear photonics, light-harvesting, and light-emitting devices.
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