分解水
剥脱关节
材料科学
硫代磷酸盐
电化学
钯
拉曼光谱
催化作用
X射线光电子能谱
带隙
电解质
化学工程
无机化学
光催化
电极
锂(药物)
石墨烯
化学
纳米技术
光电子学
物理化学
光学
内分泌学
工程类
有机化学
物理
医学
生物化学
作者
Bing Wu,Roman Kempt,Evgeniya Kovalska,Jan Luxa,Agnieszka Kuc,Thomas Heine,Zdeněk Sofer
出处
期刊:ACS applied nano materials
[American Chemical Society]
日期:2021-01-11
卷期号:4 (1): 441-448
被引量:9
标识
DOI:10.1021/acsanm.0c02775
摘要
Efficient photoelectrocatalytic (PEC) water splitting could be the solution for environmental and energy problems by converting light energy into clean and renewable energy of H2. Here, we explored 2D palladium thiophosphate Pd3(PS4)2, which is a promising photocatalyst absorbing light in the visible range. We obtained a few-layer Pd3(PS4)2 through lithium-assisted exfoliation from the bulk phase and characterized it employing Raman spectroscopy, XPS, AFM, and STM combined with DFT calculations. The measured band gap for as-obtained few-layer Pd3(PS4)2 is 2.57 eV (indirect), and its band edges span the electrochemical potentials of the hydrogen and oxygen evolution reactions. The performance in the water-splitting reaction is studied under acidic, neutral, and alkaline conditions under violet irradiation at 420 nm. 2D palladium phosphochalcogenides semiconductor with bifunctional electrocatalytic and photoelectrocatalytic properties shows competitive performance compared with industrial Pt/C catalysts for solar-driven water splitting under acidic and alkaline conditions.
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