In Situ Growth of Three-Dimensional MXene/Metal-Organic Framework Composites for High-Performance Supercapacitors.

In this study, we propose a versatile method for synthesizing uniform three-dimensional (3D) metal carbides, nitrides, and carbonitrides (MXenes)/metal-organic frameworks (MOFs) composites (Ti 3 C 2 T X /Cu-BTC, Ti 3 C 2 T X /Fe,Co-PBA, Ti 3 C 2 T X /ZIF-8, and Ti 3 C 2 T X /ZIF-67) that combine the advantages of MOFs and MXenes to enhance stability and improve conductivity. Subsequently, 3D hollow Ti 3 C 2 T X /ZIF-67/CoV 2 O 6 composites with excellent electron and ion transport properties derived from Ti 3 C 2 T X /ZIF-67 were synthesized. The specific capacitance of the Ti 3 C 2 T X /ZIF-67/CoV 2 O 6 electrode was 285.5 F g -1 , which is much higher than that of the ZIF-67 and Ti 3 C 2 T X /ZIF-67 electrode. This study opens a new avenue for the design and synthesis of MXene/MOF composites and complex hollow structures with tailorable structures and compositions for various applications.