阳极
煤焦油
复合数
硅
材料科学
碳纤维
电池(电)
热解
电化学
微观结构
化学工程
煤
化学
复合材料
冶金
电极
物理化学
有机化学
工程类
物理
功率(物理)
量子力学
作者
Nathan Dunlap,Seul-Cham Kim,Je Jun Jeong,Kyu Hwan Oh,Se-Hee Lee
标识
DOI:10.1016/j.ssi.2018.07.013
摘要
A simple, inexpensive and scalable method to prepare silicon‑carbon composite particles for use in all-solid-state Li-ion battery anodes is presented. The composite's electrochemically active soft-carbon matrix is formed through the pyrolysis of coal-tar-pitch, an abundant industrial waste material. Various techniques are used to characterize the physical and electrochemical properties of this pitch derived carbon. Optimization of the Si-C composite anode resulted in an all-solid-state Li-ion half-cell displaying stable specific capacities of 653.5 mAh/g (per mass electrode) and 1089.2 mAh/g (per mass Si-C composite) after 100 discharge-charge cycles. Cross sectional images of cycled electrodes, prepared via FIB milling, were taken in order to investigate the effect of silicon particle expansion on their composite microstructures.
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