Integration of coagulation-flocculation and heterogeneous photocatalysis for the treatment of pulp and paper mill effluent

A two-step process involving coagulation-flocculation followed by solar photocatalysis - based Advanced Oxidation Process (AOP) using TiO₂-Reduced Graphene Oxide (TRGO) nanocomposite as catalyst has been employed for the treatment of pulp and paper mill effluent. As the effluent is loaded with a high amount of organics with initial chemical oxygen demand (COD) as high as 3516, a pre-treatment is required before applying photocatalytic treatment. Coagulation-flocculation was identified as an effective pre-treatment strategy. Among the various coagulants tested, CuSO₄.5H₂O showed the best % COD reduction of 84 at pH 6, at a loading of 5 g/L. The primary treatment of coagulation improved the biodegradability index from 0.23 to 0.37. TRGO photocatalyst, employed in the second stage of photocatalytic treatment was synthesised by an ultrasound assisted solvothermal method and well characterised by various spectroscopic/analytical tools. The composite was found to be an efficient solar photocatalyst and achieved 1.76 and 2.1 times more COD reduction than synthesised TiO₂ and commercial P25 respectively. The final effluent after the combined treatment was neutral and the biochemical oxygen demand (BOD) and COD were 11.7 and 120 mg/L respectively which were below the given limit of National Environmental Quality Standards.