Occurrence, behaviors, and fate of per- and polyfluoroalkyl substances (PFASs) in typical municipal solid waste disposal sites

Per- and polyfluoroalkyl substances (PFASs) have become a crucial environmental concern owing to their exceptional persistence, ability to bioaccumulate within ecosystems, and potential to adversely affect biota. Products and materials containing PFASs are usually discarded into municipal solid waste (MSW) at the end of their life cycle, and the fate of PFASs may differ when different disposal methods of MSWs are employed. To date, limited research has focus on the occurrence, behaviors, and fate of PFASs emitted from various MSW disposal sites. This knowledge gap may lead to an underestimation of the contribution of MSW disposal sites as a source of PFASs in the environment. In this review, we collated publications concerning PFASs from typical MSW disposal sites (i.e., landfills, incineration plants, and composting facilities) and explored the occurrence patterns and behaviors of PFASs across various media (e.g., landfill leachate/ambient air, incineration plant leachate/ash, and compost products) in these typical MSW disposal sites. In particular, this review highlighted ultrashort-chain perfluoroalkyl acids and “unknown”/emerging PFASs. Additionally, it meticulously elucidated the use of non-specific techniques and non-target analysis for screening and identifying these overlooked PFASs. Furthermore, the composition profiles, mass loads, and ecological risks of PFASs were compared across the three typical disposal methods. To the best of our knowledge, this is the first review regarding the occurrence, behaviors, and fate of PFASs in typical MSW disposal sites on a global scale, which can help shed light on the potential environmental impacts of PFASs harbored in MSWs and guide future waste management practices.