材料科学
纳米复合材料
拉曼光谱
傅里叶变换红外光谱
热稳定性
膜
化学工程
质子交换膜燃料电池
石墨烯
聚合物
试剂
核化学
高分子化学
纳米技术
复合材料
有机化学
化学
生物化学
物理
工程类
光学
作者
Senthil Theerthagiri,K. Sumathy,Paradesi Deivanayagam,Chandran Muthiah,K. Dinakaran
摘要
Abstract Sulfonated polyphenylene sulphide sulfone (sPPSS) loaded with titania‐graphene (TiO 2 ‐GNS) was synthesized by the polycondensation method and studied their suitability towards proton exchange membrane fuel cell applications. The structural, morphological, and physic‐chemical properties of sPPSS nanocomposites containing varying amounts of (1%, 2%, 3%, and 5%) TiO 2 ‐GNS was investigated by Fourier transform infrared, H 1 ‐NMR, P‐XRD, FE‐SEM, HR‐TEM, Raman spectrum, swelling ratio (SR), water uptake, thermal analysis, oxidative stability (OS) and proton conductivity. Further, the obtained TiO 2 ‐GNS dispersed polymer membrane exhibits greatly reduced water absorption 4.44% and a less volume SR (15.6%). The 5 wt% TiO 2 ‐GNS dispersed sPPSS nanocomposites exhibited a PC value around 2.03 × 10 −2 S/cm at 110°C. The sPPSS nanocomposites membrane confirmed admirable OS with a maximum degradation of 39.15% during immersed in the Fenton reagent for 6 h at 80°C.
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