材料科学
摩擦腐蚀
腐蚀
等离子体电解氧化
生物相容性
合金
模拟体液
氧化物
冶金
镁
镁合金
电偶腐蚀
兴奋剂
极化(电化学)
化学工程
复合材料
电解质
电化学
扫描电子显微镜
化学
光电子学
电极
物理化学
工程类
作者
Y. Vangölü,Y.B. Bozkurt,H. Kovacı,A. Çelik
标识
DOI:10.1016/j.ceramint.2023.03.111
摘要
AZ31 alloy is a widely used material in biomedical applications. It is an alternative alloy for temporary implantation due to its low weight and superior biocompatibility. However, surface properties such as wear and corrosion are quite weak compared to other metallic biomaterials. It is extremely important to improve the surface properties, as these two mechanisms cause very serious material damage on Mg alloys separately or synergistically. In this context, oxidation processes are carried out with the plasma electrolytic oxidation (PEO) method, which provides very successful adhesion in alloys such as AZ31. In this study, the tribocorrosion performance of the films produced by doping Cu, B and Zn elements using PEO was investigated. The simultaneous effects of corrosion and wear mechanisms on surfaces were investigated with experiments carried out in artificial body fluid (SBF). It was concluded that the porous oxide films undergo morphological changes with the effect of additive elements, this change in morphology has a barrier effect, especially against corrosion attacks, and the improved corrosion resistance also improves the wear performance. According to the OCP measurements made under wear, the surface that showed the most noble behavior was Zn-doped (−0.71 V). A similar behavior can be mentioned for the wear test carried out together with the potentiodynamic polarization test. It minimized the Zn current density value in the structure (2.3 × 10−6 A/cm2).
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