共晶体系
板条
材料科学
腐蚀
马氏体
溶解
晶界
奥氏体
冶金
渗透(战争)
铋
渗碳体
微观结构
化学工程
运筹学
工程类
作者
M.T. Lapington,M. Zhang,Michael P. Moody,Wenbin Zhou,Michael P. Short,F. Hofmann
标识
DOI:10.1016/j.jnucmat.2023.154687
摘要
T91 samples were exposed to static liquid lead-bismuth eutectic (LBE) at 700-715°C for 250-500 hours in either an oxidising or reducing environment. Corrosion damage was characterised using electron microscopy techniques, which identified networks of LBE intrusion beneath LBE-wetted surfaces. Under reducing conditions these networks are uniformly distributed, while they appear patchier and deeper under oxidising conditions. The individual intrusions preferentially follow microstructural features, initially along prior-austenite grain boundaries, followed by penetration down martensite lath boundaries. Local depletion of Cr was observed within 4 μm of LBE intrusions and along intersecting boundaries, suggesting local Cr dissolution as the main corrosion mechanism.
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