An Active Strategy to Reduce Residual Alkali for High‐Performance Layered Oxide Cathode Materials of Sodium‐Ion Batteries

Abstract Residual alkali is one of the biggest challenges for the commercialization of sodium‐based layered transition metal oxide cathode materials since it can even inevitably appear during the production process. Herein, taking O3‐type Na 0.9 Ni 0.25 Mn 0.4 Fe 0.2 Mg 0.1 Ti 0.05 O 2 as an example, an active strategy is proposed to reduce residual alkali by slowing the cooling rate, which can be achieved in one‐step preparation method. It is suggested that slow cooling can significantly enhance the internal uniformity of the material, facilitating the reintegration of Na + into the bulk material during the calcination cooling phase, therefore substantially reducing residual alkali. The strategy can remarkably suppress the slurry gelation and gas evolution and enhance the structural stability. Compared to naturally cooled cathode materials, the capacity retention of the slowly cooled electrode material increases from 76.2% to 85.7% after 300 cycles at 1 C. This work offers a versatile approach to the development of advanced cathode materials toward practical applications.