阳极
法拉第效率
材料科学
锌
枝晶(数学)
化学工程
水溶液
金属
电偶阳极
图层(电子)
氧化还原
电化学
纳米技术
制作
电极
化学
冶金
有机化学
阴极保护
医学
几何学
数学
替代医学
物理化学
病理
工程类
作者
Zhenhua Hou,Huachao Tao,JiaXu Wang,Lulu Zhang,Xuelin Yang
标识
DOI:10.1007/s11431-022-2117-9
摘要
Metallic Zn can be used as an anode for aqueous zinc-ion batteries due to its low redox potential, rich resources, and high theoretical capacity. However, its practical application is limited by dendrite growth and side reactions. Herein, a simple in-situ growth strategy was applied to fabricate a Zn anode with a ZnO protective layer (Zn/ZnO) to lengthen the cycle life and inhibit the dendrite growth and side reactions. At 1 mA h cm−2 capacity, Zn/ZnO exhibits long-time stability (2500 h) at 1 mA cm−2 and outstanding rate capability (1000 h at 10 mA cm−2) in symmetrical cells. Furthermore, the average coulombic efficiency of the Zn/ZnO//Ti cell is 99.4%, which is desirable at 5 mA cm−2. In addition, the Zn/ZnO//MnO2 cell can maintain a specific capacity of 167.2 mA h g−1 after 800 stable cycles. This work presents a simple fabrication method for Zn anode with excellent performance and suggests the huge possibilities of implementing practically rechargeable aqueous zinc-ion batteries.
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