残液
化学
连续搅拌釜式反应器
异构化
模拟移动床
吸附
推流式反应器模型
二甲苯
对二甲苯
乙苯
动力学
化学工程
热力学
间歇式反应器
色谱法
甲苯
有机化学
物理化学
催化作用
萃取(化学)
物理
量子力学
工程类
作者
Mirjana Minceva,Pedro Sá Gomes,Vera Meshko,Alı́rio E. Rodrigues
标识
DOI:10.1016/j.cej.2007.09.033
摘要
A novel simulated moving bed reactor (SMBR) application for p-xylene production, which combines xylene isomerization and selective adsorption operating in liquid phase, at temperatures between 453 and 573 K is proposed. The SMBR unit configuration and principle of operation are explained. Experimentally determined xylenes adsorption equilibrium and kinetics parameters are used in the description of the xylene adsorption step. The reaction kinetics reported in the literature is used in the modelling of a fixed bed isomerization reactor. The equivalent true moving bed reactor (TMBR) modelling strategy is applied in modelling of the SMBR unit for p-xylene production. The steady state model assumes axial dispersion, coupled external and internal mass transfer resistances, and multicomponent Langmuir isotherms. The influence of the switching time, operating temperature and length of the reactors on process performance is presented for two different feed compositions: (A) xylenes composition is the same as in the feed used in a PAREX unit; (B) xylenes composition is the same as in the raffinate stream from the PAREX unit (both cases calculated on ethylbenzene and desorbent free basis).
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