等结构
维数之咒
金属有机骨架
羧酸盐
化学
配体(生物化学)
金属
有机化学
晶体结构
数学
吸附
生物化学
统计
受体
作者
Zeric Hulvey,Joshua D. Furman,Sara A. Turner,Min Tang,Anthony K. Cheetham
摘要
A new family of hybrid inorganic−organic materials has been synthesized using a combination of flexible bis-pyridyl ligands in conjunction with a perfluorinated or nonfluorinated benzenedicarboxylate ligand. A significant difference between the carboxylate torsion angles of the fluorinated and nonfluorinated ligands leads to the formation of markedly different structures for the two groups of materials. No isostructural phases were found, and the use of perfluorinated ligands tends to increase the dimensionality of the resulting frameworks.
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