分离压力
球体
拉普拉斯变换
硬球
拉普拉斯压力
简单(哲学)
胶体
机械
材料科学
体积分数
功能(生物学)
经典力学
热力学
化学
复合材料
物理
薄膜
纳米技术
表面张力
数学分析
数学
物理化学
进化生物学
生物
哲学
认识论
天文
作者
Andrij Trokhymchuk,Douglas Henderson,Alex Nikolov,Darsh T. Wasan
出处
期刊:Langmuir
[American Chemical Society]
日期:2001-06-30
卷期号:17 (16): 4940-4947
被引量:166
摘要
By use of the analytic result for the Laplace transform of the radial distribution function for two large hard spheres dispersed in a fluid of the smaller hard spheres, simple equations for the film interaction energy and film disjoining pressure, due to the structural and depletion forces, are derived. The proposed equations satisfy some known exact results and explicitly express the energy and pressure as a function of the film thickness and volume fraction of the small hard spheres. The predicted results for the film energy and film disjoining pressure are compared with existing computer simulation data. The proposed simple analytical expressions can be applied to understand the stability of liquid films containing colloidal particles and the stability of suspensions, foams, and emulsions.
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