四方晶系
磁化
居里温度
铁磁性
价(化学)
分析化学(期刊)
化学
旋转玻璃
凝聚态物理
电弧熔炼
公式单位
材料科学
结晶学
晶体结构
微观结构
磁场
物理
量子力学
有机化学
色谱法
作者
Jingyun Wang,Fangwei Wang,Bao-gen Shen,Qiwei Yan,Wen-shan Zhan,Chin Lin
摘要
Samples of (Nd1−xCex)6Fe13Al (x=0.1, 0.2, 0.3, 0.4, 0.5, 0.6) were prepared by arc melting and annealed for 2 weeks at 700 °C. The x-ray diffraction patterns for the (Nd1−xCex)6Fe13Al samples show that all the above-mentioned samples crystallize with the Nd6Fe13Si-type tetragonal phase. The unit-cell volume v increases first and then decreases as the Ce content increases. The Curie temperature and the spontaneous magnetization decrease almost linearly with increasing Ce concentration. All these prove the existence of the mixed valence of Ce3+ and Ce4+. A complicated temperature dependence of magnetization is observed. Although the series is ferromagnetic at high temperature, there is a low-temperature peak in each M–T curve, which is in agreement with spin-glass behavior. This phenomena is reported in 6:13:1-type compounds.
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