材料科学
离子电导率
电解质
烧结
电导率
晶界
兴奋剂
快离子导体
原材料
溶解
颗粒
化学工程
冶金
复合材料
微观结构
电极
化学
工程类
物理化学
有机化学
光电子学
作者
Kazuaki Kanai,S. Ozawa,Takahiro Kozawa,Makio Naito
标识
DOI:10.1016/j.apt.2021.08.035
摘要
Synthesis of Li6.25 Ga0.25 La3 Zr2 O12 (LLZO-Ga) solid electrolyte powder granule for all solid-state battery was investigated by applying mechanical processing of the raw powder materials adding LiF-BaF2 as a flux. The LLZO-Ga of highly crystalline was synthesized by the mechanical method using an attrition-type mill without any extra-heat assistance. When 10 mass% of LiF-BaF2 was added to the raw powder materials and 28 min processed, LLZO-Ga powder was favorably synthesized and granulated at the chamber temperature of 284 °C. The ionic conductivity of the sintered body of the LLZO-Ga granules was evaluated by impedance measurement. It revealed the high ionic conductivity of σtotal 1.0 × 10−3 S/cm. It suggests that the formation of LLZO-Ga/BaZrO3 grain boundary contributes to higher ionic conductivity adding to the high crystalline phase of LLZO-Ga.
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