化学
阿特拉津
羟基自由基
高岭石
结晶度
催化作用
降级(电信)
电子顺磁共振
激进的
化学工程
光化学
有机化学
矿物学
结晶学
杀虫剂
物理
工程类
农学
生物
电信
核磁共振
计算机科学
作者
Chunquan Li,Ying Huang,Xiongbo Dong,Zhiming Sun,Xiaodi Duan,Bangxing Ren,Shuilin Zheng,Dionysios D. Dionysiou
标识
DOI:10.1016/j.apcatb.2019.01.079
摘要
In this study, natural kaolinite, an abundant, low cost, thermally and chemically stable, and easily recyclable material was evaluated for the performance to activate peroxymonosulfate (PMS) by the degradation of atrazine. Based on radical quenching experiments and electron spinning resonance (ESR) spectra, hydroxyl radical (OH) and sulfate radical (SO4−) were identified to be the primary reactive species. The effects of catalyst loading, initial reaction pH, PMS dosage, initial atrazine concentration, and the presence of inorganic ions (Cl−, NO3−, HCO3− and H2PO4−) were also investigated in this work. Interestingly, the presence of H2PO4− enhanced the degradation efficiency of atrazine via promoting the decomposition of PMS. The transformation products were detected on a quadrupole time-of-flight liquid chromatography/mass spectrometer (Q-TOF-LC-MS) and the possible degradation pathway of atrazine was proposed. Based on comprehensive characterizations of crystal phase and crystallinity, porosity and pore structure, surface morphology, functional groups, and valence state of specific elements, the catalytic ability of natural kaolinite towards PMS is attributed to the abundant surface-bonded and structural hydroxyl groups. This study provides new insights of PMS activation by natural minerals for the degradation of refractory and deleterious contaminants in wastewater treatment.
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