介孔材料
材料科学
阳极
电解质
纳米结构
锂(药物)
电极
纳米技术
电池(电)
锂离子电池
纳米颗粒
化学工程
化学
催化作用
物理化学
功率(物理)
内分泌学
工程类
物理
医学
量子力学
生物化学
作者
Albert A. Voskanyan,Ching-Kit Ho,Kwong‐Yu Chan
标识
DOI:10.1016/j.jpowsour.2019.03.022
摘要
Metal oxides with uniform mesoporous structure demonstrate great potential as high-performance electrode materials for lithium-ion batteries. In this study, a three-dimensional δ-MnO2 nanostructure with ultralarge close-packed mesopores composed of nanoscale building crystals is synthesized on a large-scale through an energy- and time-efficient colloidal solution combustion synthesis method. Its unique structural features can accommodate large volumetric expansion/contraction during cycling, provide a shortened diffusion paths of lithium-ions, extensive contact area with electrolyte and suppress the pulverization and aggregation during charge/discharge cycles. As the anode of lithium-ion battery, δ-MnO2 shows a high lithium storage capacity of 905 mAh g−1 at 0.1 A g−1, excellent cycling performance after 200 cycles at 1 A g−1 and rate capability. This economical method with its exceptional advantages can be extended to produce other functional materials with controlled mesoporous nanostructures for high-performance lithium-ion batteries.
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