Hydroarylations of Heterobicyclic Alkenes through Rhodium‐Catalyzed Directed CH Functionalizations of S‐Aryl Sulfoximines

Rhodium-catalyzed directed CH-functionalizations have been used in hydroarylations of heterobicyclic alkenes with NH-sulfoximines. Unexpectedly, the bicyclic framework is retained, resulting in the formation of addition products being attractive intermediates for functionalized molecules that are difficult to prepare by other means.