过氧化氢
催化作用
电化学
电极
微电极
碳纤维
化学
扫描电子显微镜
碳糊电极
分析化学(期刊)
材料科学
乙醚
无机化学
核化学
循环伏安法
色谱法
有机化学
物理化学
复合材料
复合数
作者
Justyna Jędraszko,Olga A. Krysiak,Wojciech Adamiak,Wojciech Nogala,Hubert H. Girault,Marcin Opałło
标识
DOI:10.1002/celc.201600242
摘要
Here, we report hydrogen peroxide generation at the 2-nitrophenyloctyl ether (NPOE)/water interface with decamethylferrocene as an electron donor. The progress of this reaction was detected by the observation of a color change in the organic and aqueous phases in a series of shake-flask experiments. The shape change in cyclic voltammograms recorded at a carbon-paste electrode with decamethylferrocene in NPOE also indicates a (electro)catalytic reaction. Hydrogen peroxide was electrochemically detected at a Pt microelectrode tip positioned next to the carbon-paste electrode. For this purpose, scanning electrochemical microscopy (SECM) approach curves were recorded. Analogous experiments demonstrated the possibility of electrochemical regeneration of the electron donor. The (electro)catalytic effect of MoS2 on hydrogen peroxide generation was found by using both shake-flask and SECM experiments.
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