光催化
氧化磷酸化
甲烷氧化偶联
联轴节(管道)
光化学
聚合物
可见光谱
化学
化学工程
材料科学
高分子化学
光电子学
有机化学
催化作用
复合材料
生物化学
工程类
作者
Shakil Ahmed,Atul Kumar,Partha Sarathi Mukherjee
摘要
An emissive Pt(II) coordination polymer (TBP) was synthesized by assembling a benzothiadiazole-based Pt(II) acceptor (A) with a tetraphenylethene (TPE) containing donor (L). Multiple benzothiadiazole units in the polymeric array of the TBP rendered it with reactive oxygen species generation ability. TBP was found to be an excellent photocatalyst for oxidative coupling of benzylamine under visible light with full conversion within 2 hours at room temperature and reusability for multiple cycles. Such photocatalytic efficiency under ambient conditions, reusability of the catalyst, and easy separation of the product are noteworthy.
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