VO2/MoO3 Heterojunctions Artificial Optoelectronic Synapse Devices for Near‐Infrared Optical Communication

Abstract Artificial optoelectronic synapses (OES) have attracted extensive attention in brain‐inspired information processing and neuromorphic computing. However, OES at near‐infrared wavelengths have rarely been reported, seriously limiting the application in modern optical communication. Herein, high‐performance near‐infrared OES devices based on VO 2 /MoO 3 heterojunctions are presented. The textured MoO 3 films are deposited on the sputtered VO 2 film by using the glancing‐angle deposition technique to form a heterojunction device. Through tuning the oxygen defects in the VO 2 film, the fabricated VO 2 /MoO 3 heterojunction exhibits versatile electrical synaptic functions. Benefiting from the highly efficient light harvesting and the unique interface effect, the photonic synaptic characteristics, mainly including the short/long‐term plasticity and learning experience behavior are successfully realized at the O (1342 nm) and C (1550 nm) optical communication wavebands. Moreover, a single OES device can output messages accurately by converting light signals of the Morse code to distinct synaptic currents. More importantly, a 3 × 3 artificial OES array is constructed to demonstrate the impressive image perceiving and learning capabilities. This work not only indicates the feasibility of defect and interface engineering in modulating the synaptic plasticity of OES devices, but also provides effective strategies to develop advanced artificial neuromorphic visual systems for next‐generation optical communication systems.