Ag2S QDs integration with MnO2 nanosheets for the sensitive detection of Cr (VI) via the redox reaction induced photoelectrochemical variation

The heavy metal Cr (VI) will remain, accumulate, and migrate after entering the environment or ecosystem, causing serious harm to the environment. Here, a photoelectrochemical sensor was developed for Cr (VI), utilizing the Ag2S quantum dots (QDs) and MnO2 nanosheets as photoactive components. By introducing Ag2S QDs with a narrow gap, a staggered energy level match is created which effectively prevents the carrier recombination in MnO2 nanosheets, resulting in an enhanced photocurrent response. In the presence of the electron donor, l-ascorbic acid (AA), the photocurrent of the Ag2S QDs and MnO2 nanosheets modified photoelectrode is further enhanced. As AA has the ability to convert Cr (VI) to Cr (Ⅲ), the photocurrent may decline due to the decrease in the electron donors when Cr (VI) is added. This phenomenon can be utilized for the sensitive detection of Cr (VI) over a wider linear range (100 pM-30 μM) with a lower detection limit of 6.46 pM (S/N = 3). This work using the strategy that the targets induced the variations of the electron donor shows the advantages of good sensitivity and nice selectivity. The sensor holds many advantages such as simple fabrication process, economical material expense, and consistent photocurrent signals. It also holds significant potential for environmental monitoring and serves as a practical photoelectric sensing approach for detecting Cr (VI).