离子液体
碳纳米管
阴极
快离子导体
材料科学
导电体
离子
离子电导率
离子键合
电化学
化学工程
电流密度
纳米技术
电导率
电极
化学
复合材料
电解质
催化作用
有机化学
量子力学
物理化学
工程类
物理
作者
Ruibo Yan,Guanghao Zhan,Wenhua Liao,Qianqian Hu,Xiao‐Ying Huang,Xiaohui Wu
标识
DOI:10.1016/j.electacta.2022.141671
摘要
Na3V2(PO4)2O2F with a typical Na+ superionic conductor (NASICON) structure is a promising cathode material for sodium-ion batteries (SIBs) due to its unique layered structure, high energy density and fast ionic conductivity. However, the low intrinsic electronic conductivity seriously hinders the practical application of Na3V2(PO4)2O2F. In this work, ionic liquid-modified multi-walled carbon nanotubes (MWCNT-IL) were applied as a conductive network to form Na3V2(PO4)2O2F-based cathode. The highly dispersed MWCNT-IL can hinder the agglomeration growth of Na3V2(PO4)2O2F crystal and can result in the formation of uniform Na3V2(PO4)2O2F cubes of ∼1 μm which are covered evenly by conductive MWCNT-IL through COP/V bonds (denoted as [email protected]). Relying on the synergistic effect of conductive MWCNT-IL and uniform Na3V2(PO4)2O2F cubes, [email protected] cathode for SIBs can exhibit improved cycling stability and superior rate performance. The specific capacity of [email protected] can reach 107 mA h g−1 with high retention of 96.7% after 900 cycles at a current density of 1C (1C=130 mA h g−1). At a high current density of 30C, [email protected] maintains a high discharge capacity of 79 mA h g−1 after 1500 cycles. The above results provide an effective and simple method to construct advanced NASICON cathodes for SIBs.
科研通智能强力驱动
Strongly Powered by AbleSci AI