Template-directed synthesis of pomegranate-shaped zinc oxide@zeolitic imidazolate framework for visible light photocatalytic degradation of tetracycline

The development of photocatalysts for efficient tetracycline (TC) degradation under visible light is urgently needed yet remains a great challenge. Most semiconductor photocatalysts with low specific surface area are easy to agglomerate in solution and unfavorable for enriching pollutants. Herein, we present the preparation of pomegranate-shaped zinc oxide@zeolitic imidazolate framework (ZnO@ZIF-8) by in situ growth of ZIF-8 on a petal-shaped ZnO template that enhances the adsorption and photocatalytic degradation of TC. ZnO@ZIF-8 exhibits an excellent photostability and a TC photodegradation efficiency of 91% under visible light (λ > 420 nm) in 50 min at room temperature, which can be recycled over five times without any loss of activity. Moreover, the plausible photocatalysis reaction mechanism and the degradation intermediates are elucidated with the aid of three-dimensional excitation-emission matrix spectra and liquid chromatography-mass spectrometry system. This study offers new insights into the design of antibiotic degradation photocatalysts and the development of photocatalysts with broad-spectrum responses for efficient TC elimination.